Influence of the nature of the base electrolyte on the regioselectivity of the cathodic hydrodimerization of 1-acetylnaphthalene in an aprotic medium Научная публикация
| Журнал |
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230 |
||
|---|---|---|---|
| Вых. Данные | Год: 1991, Том: 40, Номер: 2, Страницы: 372-375 Страниц : 4 DOI: 10.1007/bf00965434 | ||
| Авторы |
|
||
| Организации |
|
Реферат:
The electrolysis of 1-acetylnaphthalene at a controlled potential [DMF, Ba· (CIO4)2] leads to the formation of 5-acetyl-1,2,4,5-tetrahydro-2-methyl-2-(1-naphthyl)-1, 4-methano-3-benzoxepine (yield of 60%); this is explained by the stabilization of the dimeric dianion of the “head-tail” type by the Ba2+ cations. The formation of 2,3-dimethyl-2,3-di-(1-naphthyl)-butane-2,3-diol is observed with the acylotropic rearrangement of the intermediate anion, leading to 2-acetylnaphthalene, in the presence of lithium cations.
Библиографическая ссылка:
Gul'tyai V.P.
, Rubinskaya T.Y.
, Mendkovich A.S.
Influence of the nature of the base electrolyte on the regioselectivity of the cathodic hydrodimerization of 1-acetylnaphthalene in an aprotic medium
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1991. V.40. N2. P.372-375. DOI: 10.1007/bf00965434 OpenAlex
Influence of the nature of the base electrolyte on the regioselectivity of the cathodic hydrodimerization of 1-acetylnaphthalene in an aprotic medium
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1991. V.40. N2. P.372-375. DOI: 10.1007/bf00965434 OpenAlex
Идентификаторы БД:
| OpenAlex: | W2088869669 |
Цитирование в БД:
| БД | Цитирований |
|---|---|
| OpenAlex | 3 |