Reaction of α-hydroxyiminoacetonitrile oxides with potassium thiocyanate

Reaction of α-hydroxyiminoacetonitrile oxides with potassium thiocyanate Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1991, Volume: 40, Number: 4, Pages: 784-788 Pages count : 5 DOI: 10.1007/bf00958574

Authors

Kalinina M.I. ^1,2 , Rakitin O.A. ^1,2 , Chertanova L.F. ^1,2 , Khmel'nitskii L.I. ^1,2 , Moiseev I.K. ^1,2

Affiliations

1	N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow
2	V. V. Kuibyshev Polytechnic Institute, USSR

Potassium thiocyanate reacts with substituted α-hydroxyiminoacetonitrile oxides in acetic acid to give, unexpectedly, 5-(carbamoyl)imino-Δ2-1,4,2-oxathiazo-lines. The structure of 3-(1-adamantyl)-5-(carbamoyl)imino-Δ2-1,4,2-oxathiazo-line has been confirmed by x-ray diffraction.

Kalinina M.I. , Rakitin O.A. , Chertanova L.F. , Khmel'nitskii L.I. , Moiseev I.K.
Reaction of α-hydroxyiminoacetonitrile oxides with potassium thiocyanate
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1991. V.40. N4. P.784-788. DOI: 10.1007/bf00958574 OpenAlex

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