Novel ruthenium(ii) complexes with chelating 1,2,4-triazole NHC ligands and their catalytic activity in the transfer hydrogenation of ketones

Novel ruthenium(ii) complexes with chelating 1,2,4-triazole NHC ligands and their catalytic activity in the transfer hydrogenation of ketones Научная публикация

Журнал

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Вых. Данные

Год: 2024, Том: 34, Номер: 3, Страницы: 385-388 Страниц : 4 DOI: 10.1016/j.mencom.2024.04.023

Авторы

Chernenko Andrey Yu. ¹ , Shepelenko Konstantin E. ¹ , Minyaev Mikhail E. ² , Chernyshev Victor M. ¹

Организации

1	Platov South-Russian State Polytechnic University, 346428 Novocherkassk, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

A series of novel ruthenium(ii) complexes with nitron-type N-heterocyclic carbene ligands containing chelating (N-arylcarbamoyl)methyl or carboxymethyl groups have been synthesized. Their evaluation as precatalysts in the hydrogenation of ketones has revealed that the complex containing three N-mesityl groups (one on the carbamoyl- methyl moiety and two on the triazole moiety) is the most efficient one.

Chernenko A.Y. , Shepelenko K.E. , Minyaev M.E. , Chernyshev V.M.
Novel ruthenium(ii) complexes with chelating 1,2,4-triazole NHC ligands and their catalytic activity in the transfer hydrogenation of ketones
Mendeleev Communications. 2024. V.34. N3. P.385-388. DOI: 10.1016/j.mencom.2024.04.023 WOS Scopus OpenAlex

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