Macrocyclic Organic Peroxides: Constructing Medium and Large Cycles with O-O Bonds Review
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Chemistry
ISSN: 2624-8549 |
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Output data | Year: 2024, Volume: 6, Number: 5, Pages: 1246-1270 Pages count : 25 DOI: 10.3390/chemistry6050072 | ||
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Abstract:
Macrocycles bridge the gap between conventional small molecules and polymers. Drawing inspiration from successful carbon heteroatom-containing macrocycles, peroxide-containing macrocycles are gaining attention for enhanced bioactivity, potential chelating properties, and applications in energetic materials. This review presents the following strategies for the construction of cyclic peroxides with 10- to 36-membered frameworks: (1) the intramolecular iodocyclization of hydroperoxides, (2) the intermolecular cyclization of hydroperoxides with alkyl dihalides or carbonyls, (3) the acid-catalyzed rearrangements of ozonides or 11-membered cyclic triperoxides via oxy- or peroxycarbenium ions, and (4) the peroxidation of carbonyls targeting macrocyclic peroxides. The specific agents that allow for the selective construction of the medium and large cycles are also analyzed.
Cite:
Barsegyan Y.A.
, Vil’ V.A.
, Terent’ev A.O.
Macrocyclic Organic Peroxides: Constructing Medium and Large Cycles with O-O Bonds
Chemistry. 2024. V.6. N5. P.1246-1270. DOI: 10.3390/chemistry6050072 OpenAlex
Macrocyclic Organic Peroxides: Constructing Medium and Large Cycles with O-O Bonds
Chemistry. 2024. V.6. N5. P.1246-1270. DOI: 10.3390/chemistry6050072 OpenAlex
Identifiers:
OpenAlex: | W4403483898 |
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