Re‐Examination of Self‐Decay Chemistry of Phthalimide‐N‐oxyl Redox‐Organocatalyst for Free‐Radical CH‐Functionalization – Puzzle Begins to Come Together

Re‐Examination of Self‐Decay Chemistry of Phthalimide‐N‐oxyl Redox‐Organocatalyst for Free‐Radical CH‐Functionalization – Puzzle Begins to Come Together Full article

Journal

Chemcatchem
ISSN: 1867-3899 , E-ISSN: 1867-3880

Output data

Year: 2024, Volume: 16, Number: 20, Article number : e202400793, Pages count : DOI: 10.1002/cctc.202400793

Authors

Lopat'eva Elena R. ¹ , Krylov Igor B. ¹ , Subbotina Irina R. ¹ , Nikishin Gennady I. ¹ , Terent'ev Alexander O. ¹

Affiliations

1	Laboratory for Studies of Homolytic Reactions N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences 47 Leninsky Prospekt Moscow 119991 Russia

Quantitative EPR and NMR monitoring of phthalimide-N-oxyl radical (PINO) generation from N-hydroxyphthalimide (NHPI) and its degradation along with decay product analysis and control experiments is presented. Collected data were used to propose general picture of PINO decay, recommend conditions for PINO stability enhancement and development of improved NHPI/PINO catalyzed processes.

Lopat'eva E.R. , Krylov I.B. , Subbotina I.R. , Nikishin G.I. , Terent'ev A.O.
Re‐Examination of Self‐Decay Chemistry of Phthalimide‐N‐oxyl Redox‐Organocatalyst for Free‐Radical CH‐Functionalization – Puzzle Begins to Come Together
Chemcatchem. 2024. V.16. N20. e202400793 . DOI: 10.1002/cctc.202400793 Scopus OpenAlex

Scopus:	2-s2.0-85200355196
OpenAlex:	W4399779429

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