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Nitroylides. 4. Synthesis of selenonium nitroylides and their conversions Научная публикация

Журнал Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230
Вых. Данные Год: 1978, Том: 27, Номер: 5, Страницы: 945-951 Страниц : 7 DOI: 10.1007/bf00928998
Авторы Shevelev S.A. 1 , Semenov V.V. 1 , Fainzil'berg A.A. 1
Организации
1 N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

Реферат: 1. Selenonium nitroylides have been synthesized, and some of their conversions have been studied. 2. Selenonium dinitroylides are split by electrophilic reagents such as hydrogen halides, SO2C12, SO2FCl, PhSCl, N-halosuccinimides, and NO2 +BF4 − at the bond, yielding halothio or nitro derivatives of dinitromethane. 3. The α-nitro-substituted selenonium salt [Ph2+SeCH(NO2)2]FSO3 − has been synthesized for the first time, and it has been shown that it is easily split by various electrophiles at the bond.
Библиографическая ссылка: Shevelev S.A. , Semenov V.V. , Fainzil'berg A.A.
Nitroylides. 4. Synthesis of selenonium nitroylides and their conversions
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1978. Т.27. №5. С.945-951. DOI: 10.1007/bf00928998 OpenAlex
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