Interaction of Difluorocarbene with the Thiocyanate Anion: Access to a Silicon Reagent Bearing the Isothiocyanate Group Научная публикация
| Журнал |
Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052 |
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| Вых. Данные | Год: 2024, Том: 26, Страницы: 10589-10593 Страниц : 5 DOI: 10.1021/acs.orglett.4c04038 | ||
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Реферат:
The reaction between (bromodifluoromethyl)trimethylsilane (TMSCF2Br) and potassium thiocyanate providing TMSCF2NCS is described. The process involves the interaction of difluorocarbene with the nitrogen atom of the thiocyanate anion. The obtained silicon reagent served as a source of the fluorinated group and difluorocarbene in the reaction with N-alkyl imines, affording 2-(difluoromethylthio)-4-fluoroimidazoles.
Библиографическая ссылка:
Trifonov A.L.
, Dilman A.D.
Interaction of Difluorocarbene with the Thiocyanate Anion: Access to a Silicon Reagent Bearing the Isothiocyanate Group
Organic Letters. 2024. V.26. P.10589-10593. DOI: 10.1021/acs.orglett.4c04038 WOS OpenAlex
Interaction of Difluorocarbene with the Thiocyanate Anion: Access to a Silicon Reagent Bearing the Isothiocyanate Group
Organic Letters. 2024. V.26. P.10589-10593. DOI: 10.1021/acs.orglett.4c04038 WOS OpenAlex
Идентификаторы БД:
| Web of science: | WOS:001363834500001 |
| OpenAlex: | W4404721319 |
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