Nitroylides 5. Synthesis and some reactions of iodonium nitroylides and α-nitro-substituted iodonium salts Научная публикация
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Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230 |
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| Вых. Данные | Год: 1978, Том: 27, Номер: 10, Страницы: 2080-2086 Страниц : 7 DOI: 10.1007/bf00946532 | ||
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Реферат:
1. We have synthesized iodonium nitroylides and examined some of their reactions. 2. Iodonium dinitroylides are cleaved by electrophiles such as halogens, N-halosuccimides, and PhSCl, giving halogen or thio derivatives of dinitromethane; the reaction with HCl forms dinitromethane. 3. We have prepared the firstα-nitro-substituted iodonium salts (A−=FSO −3 ,Cl−) and have shown that they are easily cleaved at the C(NO2) bond by nucleophiles and electrophiles.
Библиографическая ссылка:
Semenov V.V.
, Shevelev S.A.
, Fainzil'berg A.A.
Nitroylides 5. Synthesis and some reactions of iodonium nitroylides and α-nitro-substituted iodonium salts
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1978. V.27. N10. P.2080-2086. DOI: 10.1007/bf00946532 OpenAlex
Nitroylides 5. Synthesis and some reactions of iodonium nitroylides and α-nitro-substituted iodonium salts
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1978. V.27. N10. P.2080-2086. DOI: 10.1007/bf00946532 OpenAlex
Идентификаторы БД:
| OpenAlex: | W2951563937 |
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