Nitroylides 5. Synthesis and some reactions of iodonium nitroylides and α-nitro-substituted iodonium salts

Nitroylides 5. Synthesis and some reactions of iodonium nitroylides and α-nitro-substituted iodonium salts Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1978, Volume: 27, Number: 10, Pages: 2080-2086 Pages count : 7 DOI: 10.1007/bf00946532

Authors

Semenov V.V. ¹ , Shevelev S.A. ¹ , Fainzil'berg A.A. ¹

Affiliations

1	N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

1. We have synthesized iodonium nitroylides and examined some of their reactions. 2. Iodonium dinitroylides are cleaved by electrophiles such as halogens, N-halosuccimides, and PhSCl, giving halogen or thio derivatives of dinitromethane; the reaction with HCl forms dinitromethane. 3. We have prepared the firstα-nitro-substituted iodonium salts (A−=FSO −3 ,Cl−) and have shown that they are easily cleaved at the C(NO2) bond by nucleophiles and electrophiles.

Semenov V.V. , Shevelev S.A. , Fainzil'berg A.A.
Nitroylides 5. Synthesis and some reactions of iodonium nitroylides and α-nitro-substituted iodonium salts
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1978. V.27. N10. P.2080-2086. DOI: 10.1007/bf00946532 OpenAlex

OpenAlex:

W2951563937

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