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Nitroylides. 1. Synthesis and some properties of sulfonium dinitroylides Научная публикация

Журнал Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230
Вых. Данные Год: 1976, Том: 25, Номер: 9, Страницы: 1906-1909 Страниц : 4 DOI: 10.1007/bf00921718
Авторы Shevelev S.A. 1 , Semenov V.V. 1 , Fainzil'berg A.A. 1
Организации
1 N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

Реферат: 1. We have synthesized sulfonium dinitroylides of the type R2 S+---C(NO2) 2and confirmed their nitroearbanion structure. 2. Protonation of the sulfonium dinitroylides by sulfuric acid forms the dinitromethylsulfonium salts. 3. We have determined the basicity of dimethylsulfonium dinitromethylide, (CH3)2 S+--C(NO2)2 , by a spectrophotometric method.
Библиографическая ссылка: Shevelev S.A. , Semenov V.V. , Fainzil'berg A.A.
Nitroylides. 1. Synthesis and some properties of sulfonium dinitroylides
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1976. Т.25. №9. С.1906-1909. DOI: 10.1007/bf00921718 OpenAlex
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