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Nitroylides. 1. Synthesis and some properties of sulfonium dinitroylides Full article

Journal Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230
Output data Year: 1976, Volume: 25, Number: 9, Pages: 1906-1909 Pages count : 4 DOI: 10.1007/bf00921718
Authors Shevelev S.A. 1 , Semenov V.V. 1 , Fainzil'berg A.A. 1
Affiliations
1 N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow

Abstract: 1. We have synthesized sulfonium dinitroylides of the type R2 S+---C(NO2) 2and confirmed their nitroearbanion structure. 2. Protonation of the sulfonium dinitroylides by sulfuric acid forms the dinitromethylsulfonium salts. 3. We have determined the basicity of dimethylsulfonium dinitromethylide, (CH3)2 S+--C(NO2)2 , by a spectrophotometric method.
Cite: Shevelev S.A. , Semenov V.V. , Fainzil'berg A.A.
Nitroylides. 1. Synthesis and some properties of sulfonium dinitroylides
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1976. Т.25. №9. С.1906-1909. DOI: 10.1007/bf00921718 OpenAlex
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OpenAlex: W2333141755
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