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Light‐Mediated Radical Addition to Azomethine Compounds: Novel Reactivity and Activation Modes Обзор

Журнал Chemical Record
ISSN: 1527-8999 , E-ISSN: 1528-0691
Вых. Данные Год: 2025, Том: 25, Номер: 1, Номер статьи : e202400194, Страниц : DOI: 10.1002/tcr.202400194
Авторы Rubanov Zakhar M. 1 , Levin Vitalij V. 1 , Dilman Alexander D. 1
Организации
1 N. D. Zelinsky Institute of Organic Chemistry Leninsky prosp. 47 119991 Moscow Russian Federation

Реферат: Azomethines is a class of compounds, which have traditionally served as electrophilic substrates, but their reactions with radicals have long been limited. Photocatalysis provided ample opportunities for promoting these reactions, with wide variety of reagents serving as precursors of radicals. Besides regular addition mode at the azomethine fragment, the oxidative pathway, in which the C=N bond remains in the product, has become possible by proper selection of redox catalyst. This review summarizes new developments in this rapidly developing field over the past five years. New concepts on activation of the C=N bond towards radical attack are discussed.
Библиографическая ссылка: Rubanov Z.M. , Levin V.V. , Dilman A.D.
Light‐Mediated Radical Addition to Azomethine Compounds: Novel Reactivity and Activation Modes
Chemical Record. 2025. V.25. N1. e202400194 . DOI: 10.1002/tcr.202400194 WOS OpenAlex
Идентификаторы БД:
Web of science: WOS:001379025300001
OpenAlex: W4405558915
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БД Цитирований
OpenAlex 1
Web of science 3
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