Light‐Mediated Radical Addition to Azomethine Compounds: Novel Reactivity and Activation Modes

Light‐Mediated Radical Addition to Azomethine Compounds: Novel Reactivity and Activation Modes Review

Journal

Chemical Record
ISSN: 1527-8999 , E-ISSN: 1528-0691

Output data

Year: 2025, Volume: 25, Number: 1, Article number : e202400194, Pages count : DOI: 10.1002/tcr.202400194

Authors

Rubanov Zakhar M. ¹ , Levin Vitalij V. ¹ , Dilman Alexander D. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry Leninsky prosp. 47 119991 Moscow Russian Federation

Azomethines is a class of compounds, which have traditionally served as electrophilic substrates, but their reactions with radicals have long been limited. Photocatalysis provided ample opportunities for promoting these reactions, with wide variety of reagents serving as precursors of radicals. Besides regular addition mode at the azomethine fragment, the oxidative pathway, in which the C=N bond remains in the product, has become possible by proper selection of redox catalyst. This review summarizes new developments in this rapidly developing field over the past five years. New concepts on activation of the C=N bond towards radical attack are discussed.

Rubanov Z.M. , Levin V.V. , Dilman A.D.
Light‐Mediated Radical Addition to Azomethine Compounds: Novel Reactivity and Activation Modes
Chemical Record. 2025. V.25. N1. e202400194 . DOI: 10.1002/tcr.202400194 WOS OpenAlex

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