Kinetics and mechanism of the reaction of nitro and halonitro compounds with potassium iodide and other reducing agents. Communication 6. Kinetics of the reaction of fluorochloro-, fluorobromo-, and fluoroiododinitromethanes with potassium iodide

Kinetics and mechanism of the reaction of nitro and halonitro compounds with potassium iodide and other reducing agents. Communication 6. Kinetics of the reaction of fluorochloro-, fluorobromo-, and fluoroiododinitromethanes with potassium iodide Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1971, Volume: 20, Number: 1, Pages: 80-83 Pages count : 4 DOI: 10.1007/bf00849324

Authors

L'vova M.Sh. ¹ , Slovetskii V.I. ¹ , Okhlobystina L.V. ¹ , Khutoretskii V.M. ¹ , Fainzil'berg A.A. ¹

Affiliations

1	N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

1. Under the action of potassium iodide on fluorohalodinitromethanes in 70% aqueous ethanol, there is a cleavage of the C- Hal bond (Hal=Cl, Br, I), with the formation of fluorodinitromethane. 2. The kinetics of the reaction of fluorochlorodinitromethane and fluorobromodinitromethane with KI in 70% aqueous ethanol was studied. These reactions proceed according to a total second order and are first order with respect to each component.

L'vova M.S. , Slovetskii V.I. , Okhlobystina L.V. , Khutoretskii V.M. , Fainzil'berg A.A.
Kinetics and mechanism of the reaction of nitro and halonitro compounds with potassium iodide and other reducing agents. Communication 6. Kinetics of the reaction of fluorochloro-, fluorobromo-, and fluoroiododinitromethanes with potassium iodide
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1971. V.20. N1. P.80-83. DOI: 10.1007/bf00849324 OpenAlex

OpenAlex:

W2326672851

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