Generation of fluoro(thio)carbenes from Me3SiCF2SAr | Sciact - научная деятельность

Generation of fluoro(thio)carbenes from Me3SiCF2SAr Научная публикация

Журнал

Journal of Fluorine Chemistry
ISSN: 1873-3328 , E-ISSN: 0022-1139

Вых. Данные

Год: 2022, Том: 261-262, Номер статьи : 110025, Страниц : DOI: 10.1016/j.jfluchem.2022.110025

Авторы

Ilin Egor A. ^1,2 , Smirnov Vladimir O. ¹ , Dilman Alexander D. ¹

Организации

1	N. D. Zelinsky Institute of Organic Chemistry, Leninsky prosp. 47, Moscow 119991, Russian Federation
2	Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1-3, Moscow 119991, Russian Federation

Generation of carbenes bearing a fluorine atom and an arylthio group from the difluorinated silicon reagents is described. The carbene generation is performed using a combination of lithium methoxide and lithium chloride, which behave as Lewis basic and Lewis acidic activators, respectively. The reactivity of fluoro(thio)carbenes was evaluated by trapping with an alkene and an aminoborane. Quantum chemical calculations allowed comparison of the fluoro(thio)carbene with difluorocarbene.

Ilin E.A. , Smirnov V.O. , Dilman A.D.
Generation of fluoro(thio)carbenes from Me3SiCF2SAr
Journal of Fluorine Chemistry. 2022. V.261-262. 110025 . DOI: 10.1016/j.jfluchem.2022.110025 WOS Scopus OpenAlex

Web of science:	WOS:000847853400001
Scopus:	2-s2.0-85136522685
OpenAlex:	W4291335357

БД	Цитирований
OpenAlex	1
Scopus	1