Generation of fluoro(thio)carbenes from Me3SiCF2SAr

Generation of fluoro(thio)carbenes from Me3SiCF2SAr Full article

Journal

Journal of Fluorine Chemistry
ISSN: 1873-3328 , E-ISSN: 0022-1139

Output data

Year: 2022, Volume: 261-262, Article number : 110025, Pages count : DOI: 10.1016/j.jfluchem.2022.110025

Authors

Ilin Egor A. ^1,2 , Smirnov Vladimir O. ¹ , Dilman Alexander D. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Leninsky prosp. 47, Moscow 119991, Russian Federation
2	Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1-3, Moscow 119991, Russian Federation

Generation of carbenes bearing a fluorine atom and an arylthio group from the difluorinated silicon reagents is described. The carbene generation is performed using a combination of lithium methoxide and lithium chloride, which behave as Lewis basic and Lewis acidic activators, respectively. The reactivity of fluoro(thio)carbenes was evaluated by trapping with an alkene and an aminoborane. Quantum chemical calculations allowed comparison of the fluoro(thio)carbene with difluorocarbene.

Ilin E.A. , Smirnov V.O. , Dilman A.D.
Generation of fluoro(thio)carbenes from Me3SiCF2SAr
Journal of Fluorine Chemistry. 2022. V.261-262. 110025 . DOI: 10.1016/j.jfluchem.2022.110025 WOS Scopus OpenAlex

Web of science:	WOS:000847853400001
Scopus:	2-s2.0-85136522685
OpenAlex:	W4291335357

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OpenAlex	1
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