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Reaction of 2-methyl-2-phenylpropylmagnesium chloride with allyl and 2-methylallyl chlorides Научная публикация

Журнал Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230
Вых. Данные Год: 1957, Том: 6, Номер: 8, Страницы: 1035-1037 Страниц : 3 DOI: 10.1007/bf01173607
Авторы Petrov A.D. 1,2 , Nefedov O.M. 1,2 , Ogibin Yu.N. 1,2
Организации
1 D. I. Mendeleev Institute of Chemical Technology Moscow, USSR
2 N. D. Zelinsky Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

Реферат: 1. It was shown that 2-methyl-2-phenylpropylmagnesium chloride does not react with isobutyl halides, but it condenses with allyl and 2-methylallyl chlorides with formation of the corresponding hydrocarbons in high yield (70% and 51%). 2. The freezing points of the branched alkylbenzenes and alkylcyclohexanes synthesized range from −70° to −90° and are lower by 30–45° than the freezing points of the isomeric hydrocarbons having normal paraffin chains.
Библиографическая ссылка: Petrov A.D. , Nefedov O.M. , Ogibin Y.N.
Reaction of 2-methyl-2-phenylpropylmagnesium chloride with allyl and 2-methylallyl chlorides
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1957. V.6. N8. P.1035-1037. DOI: 10.1007/bf01173607 OpenAlex
Идентификаторы БД:
OpenAlex: W2049098930
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