Reaction of 2-methyl-2-phenylpropylmagnesium chloride with allyl and 2-methylallyl chlorides

Reaction of 2-methyl-2-phenylpropylmagnesium chloride with allyl and 2-methylallyl chlorides Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1957, Volume: 6, Number: 8, Pages: 1035-1037 Pages count : 3 DOI: 10.1007/bf01173607

Authors

Petrov A.D. ^1,2 , Nefedov O.M. ^1,2 , Ogibin Yu.N. ^1,2

Affiliations

1	D. I. Mendeleev Institute of Chemical Technology Moscow, USSR
2	N. D. Zelinsky Institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

1. It was shown that 2-methyl-2-phenylpropylmagnesium chloride does not react with isobutyl halides, but it condenses with allyl and 2-methylallyl chlorides with formation of the corresponding hydrocarbons in high yield (70% and 51%). 2. The freezing points of the branched alkylbenzenes and alkylcyclohexanes synthesized range from −70° to −90° and are lower by 30–45° than the freezing points of the isomeric hydrocarbons having normal paraffin chains.

Petrov A.D. , Nefedov O.M. , Ogibin Y.N.
Reaction of 2-methyl-2-phenylpropylmagnesium chloride with allyl and 2-methylallyl chlorides
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1957. V.6. N8. P.1035-1037. DOI: 10.1007/bf01173607 OpenAlex

OpenAlex:

W2049098930

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