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Perchlorylamino furazans and their salts: new high-energy-density materials with high sensitivity Научная публикация

Журнал Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436
Вых. Данные Год: 2020, Том: 30, Номер: 4, Страницы: 490-493 Страниц : 4 DOI: 10.1016/j.mencom.2020.07.028
Авторы Sheremetev Aleksei B. 1
Организации
1 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

Реферат: The first perchlorylamino heterocycles, perchlorylaminofurazans, were obtained by the reaction of N-lithiated and N-silylated aminofurazans with FClO3 or Cl2O7. Energetic salts comprising nitrogen-rich 1,2,4-triazolbased cations and 3-nitro-4-(perchlorylamino)furazan anion whose predicted explosive performance was close or superior to that of HMX were synthesized and characterized. Although the explosive output of perchlorylaminofurazan salts is better compared to relative nitraminofurazan ones, they would more readily degrade (explode!) upon impact, friction or heating.
Библиографическая ссылка: Sheremetev A.B.
Perchlorylamino furazans and their salts: new high-energy-density materials with high sensitivity
Mendeleev Communications. 2020. V.30. N4. P.490-493. DOI: 10.1016/j.mencom.2020.07.028 WOS Scopus OpenAlex
Идентификаторы БД:
≡ Web of science: WOS:000557884000028
≡ Scopus: 2-s2.0-85088992450
≡ OpenAlex: W3047460206
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