Perchlorylamino furazans and their salts: new high-energy-density materials with high sensitivity

Perchlorylamino furazans and their salts: new high-energy-density materials with high sensitivity Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2020, Volume: 30, Number: 4, Pages: 490-493 Pages count : 4 DOI: 10.1016/j.mencom.2020.07.028

Authors

Sheremetev Aleksei B. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

The first perchlorylamino heterocycles, perchlorylaminofurazans, were obtained by the reaction of N-lithiated and N-silylated aminofurazans with FClO3 or Cl2O7. Energetic salts comprising nitrogen-rich 1,2,4-triazolbased cations and 3-nitro-4-(perchlorylamino)furazan anion whose predicted explosive performance was close or superior to that of HMX were synthesized and characterized. Although the explosive output of perchlorylaminofurazan salts is better compared to relative nitraminofurazan ones, they would more readily degrade (explode!) upon impact, friction or heating.

Sheremetev A.B.
Perchlorylamino furazans and their salts: new high-energy-density materials with high sensitivity
Mendeleev Communications. 2020. V.30. N4. P.490-493. DOI: 10.1016/j.mencom.2020.07.028 WOS Scopus OpenAlex

≡ Web of science:	WOS:000557884000028
≡ Scopus:	2-s2.0-85088992450
≡ OpenAlex:	W3047460206