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Synthesis and properties of (1-methylallyl)- and 2-butenyl-silanes Научная публикация

Журнал Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230
Вых. Данные Год: 1954, Том: 3, Номер: 3, Страницы: 429-434 Страниц : 6 DOI: 10.1007/bf01167821
Авторы Petrov A.D. 1 , Ponomarenko V.A. 1 , Boikov V.I. 1
Организации
1 N. D. Zelinsky Institute of organic Chemistry of the USSR Academy of Sciences, USSR

Реферат: 1. t has been shown that in the Grignard-Wurtz synthesis of alkenylsilanes from 1-bromo-2-butenes, the latter undergo the same type of allyl rearrangement as in the synthesis of hydrocarbons, i.e., in the condensation of R- MgX are formed. When R-X is condensed with is formed. 2. Silicon analogs of olefins have been synthesized: (1-methylallyl)silane, 2-butenylsilane, methyl(1-methylallyl)silane, trichloro(1-methylallyl)silane, triethyl(1-methylallyl)silane, and trimethyl-3-pentenylsilane.
Библиографическая ссылка: Petrov A.D. , Ponomarenko V.A. , Boikov V.I.
Synthesis and properties of (1-methylallyl)- and 2-butenyl-silanes
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1954. V.3. N3. P.429-434. DOI: 10.1007/bf01167821 OpenAlex
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OpenAlex: W2004367579
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