Synthesis and properties of (1-methylallyl)- and 2-butenyl-silanes Full article
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Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230 |
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| Output data | Year: 1954, Volume: 3, Number: 3, Pages: 429-434 Pages count : 6 DOI: 10.1007/bf01167821 | ||
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Abstract:
1. t has been shown that in the Grignard-Wurtz synthesis of alkenylsilanes from 1-bromo-2-butenes, the latter undergo the same type of allyl rearrangement as in the synthesis of hydrocarbons, i.e., in the condensation of R- MgX are formed. When R-X is condensed with is formed. 2. Silicon analogs of olefins have been synthesized: (1-methylallyl)silane, 2-butenylsilane, methyl(1-methylallyl)silane, trichloro(1-methylallyl)silane, triethyl(1-methylallyl)silane, and trimethyl-3-pentenylsilane.
Cite:
Petrov A.D.
, Ponomarenko V.A.
, Boikov V.I.
Synthesis and properties of (1-methylallyl)- and 2-butenyl-silanes
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1954. V.3. N3. P.429-434. DOI: 10.1007/bf01167821 OpenAlex
Synthesis and properties of (1-methylallyl)- and 2-butenyl-silanes
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1954. V.3. N3. P.429-434. DOI: 10.1007/bf01167821 OpenAlex
Identifiers:
| OpenAlex: | W2004367579 |
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