Low-temperature alkylation of α- and β-olefins with tertiary alkyl halides in presence of zinc chloride Научная публикация
| Журнал |
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230 |
||
|---|---|---|---|
| Вых. Данные | Год: 1956, Том: 5, Номер: 1, Страницы: 65-70 Страниц : 6 DOI: 10.1007/bf01178014 | ||
| Авторы |
|
||
| Организации |
|
Реферат:
1. A study was made of low-temperature alkylation of olefine with tertiary alkyl halides in presence of zinc chloride, and the relationship between the structure of the reactants and the character of the side reactions — isomeric changes accompanying the reaction of addition of chloroalkans to alkaŋes — was elucidated. 2. It was established that in the alkylation of 2-butene, both with tert-butyl chloride and with 2-chloro-2, 3-dimethylbutane. the octene and decene isomers predicted by theory are formed. 3. I the alkylation of 2-methyl-2butene with tert-butyl chloride, only one isometric form of the expected structure is formed (2,3,3,4-tetramethyl-4-heptene), and in alkylation with 2-chloro-2,3,3-trimethylbutane, again only one isomeric form (2,3,3,4,40pentamethyl-1-hexene).
Библиографическая ссылка:
Meshcheryakov A.P.
, Erzyutova E.I.
, Petrov A.D.
Low-temperature alkylation of α- and β-olefins with tertiary alkyl halides in presence of zinc chloride
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1956. V.5. N1. P.65-70. DOI: 10.1007/bf01178014 OpenAlex
Low-temperature alkylation of α- and β-olefins with tertiary alkyl halides in presence of zinc chloride
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1956. V.5. N1. P.65-70. DOI: 10.1007/bf01178014 OpenAlex
Идентификаторы БД:
| OpenAlex: | W2090517344 |
Цитирование в БД:
Пока нет цитирований