Low-temperature alkylation of α- and β-olefins with tertiary alkyl halides in presence of zinc chloride

Low-temperature alkylation of α- and β-olefins with tertiary alkyl halides in presence of zinc chloride Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1956, Volume: 5, Number: 1, Pages: 65-70 Pages count : 6 DOI: 10.1007/bf01178014

Authors

Meshcheryakov A.P. ¹ , Erzyutova E.I. ¹ , Petrov A.D. ¹

Affiliations

1	N. D. Zelinsky institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

1. A study was made of low-temperature alkylation of olefine with tertiary alkyl halides in presence of zinc chloride, and the relationship between the structure of the reactants and the character of the side reactions — isomeric changes accompanying the reaction of addition of chloroalkans to alkaŋes — was elucidated. 2. It was established that in the alkylation of 2-butene, both with tert-butyl chloride and with 2-chloro-2, 3-dimethylbutane. the octene and decene isomers predicted by theory are formed. 3. I the alkylation of 2-methyl-2butene with tert-butyl chloride, only one isometric form of the expected structure is formed (2,3,3,4-tetramethyl-4-heptene), and in alkylation with 2-chloro-2,3,3-trimethylbutane, again only one isomeric form (2,3,3,4,40pentamethyl-1-hexene).

Meshcheryakov A.P. , Erzyutova E.I. , Petrov A.D.
Low-temperature alkylation of α- and β-olefins with tertiary alkyl halides in presence of zinc chloride
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1956. V.5. N1. P.65-70. DOI: 10.1007/bf01178014 OpenAlex

OpenAlex:

W2090517344

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