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Synthesis and reactions of oxygen-containing organosilicon compounds. Communication 3. Synthesis and some reactions of vinyl ethers of 3-(trimethylsilyl)- and 3-(diethylmethylsilyl)-1-propanol Научная публикация

Журнал Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230
Вых. Данные Год: 1956, Том: 5, Номер: 12, Страницы: 1535-1541 Страниц : 7 DOI: 10.1007/bf01177536
Авторы Shostakovsky M.F. 1 , Shikhiev I.A. 1 , Komarov N.V. 1
Организации
1 N. D. Zelinsky institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

Реферат: 1. The vinyl ether of 3-(diethylmethylsilyl)-1-propanol was synthesized by a modification of the Favorsky-Shostakovsky method. 2. A study was made of the reactions of the vinyl ethers of 3-(trimethylsilyl)- and 3-(diethylmethylsilyl)-1-propanol with water, organic and organosilicon alcohols, and organic acids. 3. 3-(Diethylmethylsilyl)-1-propanol, its vinyl ether, four organosilicon acetals, and three acylals were prepared for the first time. 4. It was shown that, under similar conditions, the vinyl ether of 3-(diethylmethylsilyl)-1-propanol and organosilicon acetals and acylals are hydrolyzed with greater difficulty than their organic analogs.
Библиографическая ссылка: Shostakovsky M.F. , Shikhiev I.A. , Komarov N.V.
Synthesis and reactions of oxygen-containing organosilicon compounds. Communication 3. Synthesis and some reactions of vinyl ethers of 3-(trimethylsilyl)- and 3-(diethylmethylsilyl)-1-propanol
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1956. V.5. N12. P.1535-1541. DOI: 10.1007/bf01177536 OpenAlex
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