Synthesis and reactions of oxygen-containing organosilicon compounds. Communication 3. Synthesis and some reactions of vinyl ethers of 3-(trimethylsilyl)- and 3-(diethylmethylsilyl)-1-propanol

Synthesis and reactions of oxygen-containing organosilicon compounds. Communication 3. Synthesis and some reactions of vinyl ethers of 3-(trimethylsilyl)- and 3-(diethylmethylsilyl)-1-propanol Full article

Journal

Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230

Output data

Year: 1956, Volume: 5, Number: 12, Pages: 1535-1541 Pages count : 7 DOI: 10.1007/bf01177536

Authors

Shostakovsky M.F. ¹ , Shikhiev I.A. ¹ , Komarov N.V. ¹

Affiliations

1	N. D. Zelinsky institute of Organic Chemistry of the Academy of Sciences of the USSR, USSR

1. The vinyl ether of 3-(diethylmethylsilyl)-1-propanol was synthesized by a modification of the Favorsky-Shostakovsky method. 2. A study was made of the reactions of the vinyl ethers of 3-(trimethylsilyl)- and 3-(diethylmethylsilyl)-1-propanol with water, organic and organosilicon alcohols, and organic acids. 3. 3-(Diethylmethylsilyl)-1-propanol, its vinyl ether, four organosilicon acetals, and three acylals were prepared for the first time. 4. It was shown that, under similar conditions, the vinyl ether of 3-(diethylmethylsilyl)-1-propanol and organosilicon acetals and acylals are hydrolyzed with greater difficulty than their organic analogs.

Shostakovsky M.F. , Shikhiev I.A. , Komarov N.V.
Synthesis and reactions of oxygen-containing organosilicon compounds. Communication 3. Synthesis and some reactions of vinyl ethers of 3-(trimethylsilyl)- and 3-(diethylmethylsilyl)-1-propanol
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1956. V.5. N12. P.1535-1541. DOI: 10.1007/bf01177536 OpenAlex

OpenAlex:

W2094715199

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