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Synthesis and transformations of unsaturated organosilicon compounds. Communication 2. Synthesis of tertiary trihydric γ-silicon-containing alcohols of the acetylenic series Научная публикация

Журнал Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230
Вых. Данные Год: 1957, Том: 6, Номер: 9, Страницы: 1168-1171 Страниц : 4 DOI: 10.1007/bf01169403
Авторы Shikhtev I.A. 1 , Shostakovsky M.F. 1 , Komarov N.V. 1 , Kayutenko L.A. 1
Организации
1 N. D. Zelinsky Institute of Organic Chemistry of the Academy of Sciences, USSR

Реферат: 1. The interaction of trichlorosilane, methyltrichlorosilane and vinyltrichlorosilane with the mixed alcoholate of dimethylethynyl carbinol-magnesium bromide was investigated. The reactions yielded three representatives of a new class of organosilicon compounds - trihydric tertiaryγ-silicon-containing alcohols of the acetylenic series. 2. A method of preparation of trihydric tertiaryγ-silicon-containing acetylenic alcohols was developed on the basis of the reaction of alkyltrichlorosilanes with dimethylethynyl carbinol-magnesium bromide.
Библиографическая ссылка: Shikhtev I.A. , Shostakovsky M.F. , Komarov N.V. , Kayutenko L.A.
Synthesis and transformations of unsaturated organosilicon compounds. Communication 2. Synthesis of tertiary trihydric γ-silicon-containing alcohols of the acetylenic series
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1957. V.6. N9. P.1168-1171. DOI: 10.1007/bf01169403 OpenAlex
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