Synthesis and transformations of unsaturated organosilicon compounds. Communication 2. Synthesis of tertiary trihydric γ-silicon-containing alcohols of the acetylenic series Full article
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Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science
ISSN: 2376-8444 , E-ISSN: 0568-5230 |
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| Output data | Year: 1957, Volume: 6, Number: 9, Pages: 1168-1171 Pages count : 4 DOI: 10.1007/bf01169403 | ||
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Abstract:
1. The interaction of trichlorosilane, methyltrichlorosilane and vinyltrichlorosilane with the mixed alcoholate of dimethylethynyl carbinol-magnesium bromide was investigated. The reactions yielded three representatives of a new class of organosilicon compounds - trihydric tertiaryγ-silicon-containing alcohols of the acetylenic series. 2. A method of preparation of trihydric tertiaryγ-silicon-containing acetylenic alcohols was developed on the basis of the reaction of alkyltrichlorosilanes with dimethylethynyl carbinol-magnesium bromide.
Cite:
Shikhtev I.A.
, Shostakovsky M.F.
, Komarov N.V.
, Kayutenko L.A.
Synthesis and transformations of unsaturated organosilicon compounds. Communication 2. Synthesis of tertiary trihydric γ-silicon-containing alcohols of the acetylenic series
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1957. V.6. N9. P.1168-1171. DOI: 10.1007/bf01169403 OpenAlex
Synthesis and transformations of unsaturated organosilicon compounds. Communication 2. Synthesis of tertiary trihydric γ-silicon-containing alcohols of the acetylenic series
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science. 1957. V.6. N9. P.1168-1171. DOI: 10.1007/bf01169403 OpenAlex
Identifiers:
| OpenAlex: | W1967979339 |
Citing:
| DB | Citing |
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| OpenAlex | 1 |