Nucleophilic substitution in azasydnone-modified dinitroanisoles | Sciact

Nucleophilic substitution in azasydnone-modified dinitroanisoles Научная публикация

Журнал

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Вых. Данные

Год: 2025, Том: 35, Номер: 3, Страницы: 271-273 Страниц : 3 DOI: 10.71267/mencom.7614

Авторы

Shkineva Tatiana Konstantinovna ¹ , Kormanov Alexander Vasilyvich ¹ , Dalinger Igor L'vovich ¹

Организации

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

Reactions of 3-(4-methoxy-3,5-dinitrophenyl)-1,2,3,4-oxatriazolium-5-olate with N-nucleophiles under mild conditions results in the displacement of the methoxy group leaving 1,2,3,4-oxatriazolium-5-olate (azasydnone) moiety intact. In the case of alkylhydrazines, further cyclization involving nitro group into benzo[d][1,2,3]triazole 3-oxides occurs.

Shkineva T.K. , Kormanov A.V. , Dalinger I.L.
Nucleophilic substitution in azasydnone-modified dinitroanisoles
Mendeleev Communications. 2025. V.35. N3. P.271-273. DOI: 10.71267/mencom.7614 WOS Scopus OpenAlex

≡ Web of science:	WOS:001501365000010
≡ Scopus:	2-s2.0-105006796711
≡ OpenAlex:	W4409003307