Nucleophilic substitution in azasydnone-modified dinitroanisoles

Nucleophilic substitution in azasydnone-modified dinitroanisoles Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2025, Volume: 35, Number: 3, Pages: 271-273 Pages count : 3 DOI: 10.71267/mencom.7614

Authors

Shkineva Tatiana Konstantinovna ¹ , Kormanov Alexander Vasilyvich ¹ , Dalinger Igor L'vovich ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

Reactions of 3-(4-methoxy-3,5-dinitrophenyl)-1,2,3,4-oxatriazolium-5-olate with N-nucleophiles under mild conditions results in the displacement of the methoxy group leaving 1,2,3,4-oxatriazolium-5-olate (azasydnone) moiety intact. In the case of alkylhydrazines, further cyclization involving nitro group into benzo[d][1,2,3]triazole 3-oxides occurs.

Shkineva T.K. , Kormanov A.V. , Dalinger I.L.
Nucleophilic substitution in azasydnone-modified dinitroanisoles
Mendeleev Communications. 2025. V.35. N3. P.271-273. DOI: 10.71267/mencom.7614 WOS Scopus OpenAlex

≡ Web of science:	WOS:001501365000010
≡ Scopus:	2-s2.0-105006796711
≡ OpenAlex:	W4409003307