Copper/Bis(imine)‐Catalyzed Fluoroalkylative Thiocyanation of Unactivated Alkenes

Copper/Bis(imine)‐Catalyzed Fluoroalkylative Thiocyanation of Unactivated Alkenes Научная публикация

Журнал

European Journal of Organic Chemistry
ISSN: 1434-193X , E-ISSN: 1099-0690

Вых. Данные

Год: 2025, Том: 28, Номер: 27, Номер статьи : e202500393, Страниц : DOI: 10.1002/ejoc.202500393

Авторы

Peresypkin Leonid A. ^1,2 , Kostromitin Vladislav S. ^1,2 , Levin Vitalij.V. ¹ , Dilman Alexander ¹

Организации

1	N. D. Zelinsky Institute of Organic Chemistry, Leninsky prosp. 47, 119991 Moscow, Russian Federation
2	Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1–3, 119991 Moscow, Russian Federation

A method for the radical difunctionalization of nonactivated alkenes using fluorinated halides and thiocyanate anion is described. A combination of cheap copper(I) thiocyanate with a readily accessible bis(imine) ligand promoted the reaction under purple light irradiation without additional photocatalyst. The method is applicable to chloro- and bromodifluoroacetate, as well as to other fluorinated bromides, and tolerates a wide variety of functional groups.

Peresypkin L.A. , Kostromitin V.S. , Levin V.V. , Dilman A.
Copper/Bis(imine)‐Catalyzed Fluoroalkylative Thiocyanation of Unactivated Alkenes
European Journal of Organic Chemistry. 2025. V.28. N27. e202500393 . DOI: 10.1002/ejoc.202500393 OpenAlex

OpenAlex:

W4411046314

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