Copper/Bis(imine)‐Catalyzed Fluoroalkylative Thiocyanation of Unactivated Alkenes Full article
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European Journal of Organic Chemistry
ISSN: 1434-193X , E-ISSN: 1099-0690 |
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Output data | Year: 2025, Volume: 28, Number: 27, Article number : e202500393, Pages count : DOI: 10.1002/ejoc.202500393 | ||||
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Abstract:
A method for the radical difunctionalization of nonactivated alkenes using fluorinated halides and thiocyanate anion is described. A combination of cheap copper(I) thiocyanate with a readily accessible bis(imine) ligand promoted the reaction under purple light irradiation without additional photocatalyst. The method is applicable to chloro- and bromodifluoroacetate, as well as to other fluorinated bromides, and tolerates a wide variety of functional groups.
Cite:
Peresypkin L.A.
, Kostromitin V.S.
, Levin V.V.
, Dilman A.
Copper/Bis(imine)‐Catalyzed Fluoroalkylative Thiocyanation of Unactivated Alkenes
European Journal of Organic Chemistry. 2025. V.28. N27. e202500393 . DOI: 10.1002/ejoc.202500393 OpenAlex
Copper/Bis(imine)‐Catalyzed Fluoroalkylative Thiocyanation of Unactivated Alkenes
European Journal of Organic Chemistry. 2025. V.28. N27. e202500393 . DOI: 10.1002/ejoc.202500393 OpenAlex
Identifiers:
OpenAlex: | W4411046314 |
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