Influence of N-heterocyclic carbene modification on the catalytic performance of Pd clusters and nanoparticles in the Mizoroki--Heck reaction

Influence of N-heterocyclic carbene modification on the catalytic performance of Pd clusters and nanoparticles in the Mizoroki--Heck reaction Научная публикация

Журнал

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Вых. Данные

Год: 2026, Том: 36, Номер: 1, Страницы: 37-40 Страниц : 4 DOI: 10.71267/mencom.7806

Авторы

Kostyukovich Alexander Yur'evich ¹ , Shutovskaya Evgeniya S. ¹ , Prima Darya Olegovna ¹

Организации

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

The addition of azolium salt as N-heterocyclic carbene (NHC) proligant improved the catalytic performance of palladium nanoparticles in the Mizoroki–Heck coupling. The catalytic activity of NHC-modified palladium on carbon (Pd-NHC/C) was evaluated in reactions involving a variety of olefin and aryl bromide counterparts. Quantum chemical calculations of the full reaction pathways for both ligand-free and NHC-modified Pd2 clusters revealed a reduction in the activation energy of the second reaction route.

Kostyukovich A.Y. , Shutovskaya E.S. , Prima D.O.
Influence of N-heterocyclic carbene modification on the catalytic performance of Pd clusters and nanoparticles in the Mizoroki--Heck reaction
Mendeleev Communications. 2026. V.36. N1. P.37-40. DOI: 10.71267/mencom.7806 WOS OpenAlex

Web of science:	WOS:001629991500010
OpenAlex:	W4416804501

Пока нет цитирований