Influence of N-heterocyclic carbene modification on the catalytic performance of Pd clusters and nanoparticles in the Mizoroki--Heck reaction

Influence of N-heterocyclic carbene modification on the catalytic performance of Pd clusters and nanoparticles in the Mizoroki--Heck reaction Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2026, Volume: 36, Number: 1, Pages: 37-40 Pages count : 4 DOI: 10.71267/mencom.7806

Authors

Kostyukovich Alexander Yur'evich ¹ , Shutovskaya Evgeniya S. ¹ , Prima Darya Olegovna ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

The addition of azolium salt as N-heterocyclic carbene (NHC) proligant improved the catalytic performance of palladium nanoparticles in the Mizoroki–Heck coupling. The catalytic activity of NHC-modified palladium on carbon (Pd-NHC/C) was evaluated in reactions involving a variety of olefin and aryl bromide counterparts. Quantum chemical calculations of the full reaction pathways for both ligand-free and NHC-modified Pd2 clusters revealed a reduction in the activation energy of the second reaction route.

Kostyukovich A.Y. , Shutovskaya E.S. , Prima D.O.
Influence of N-heterocyclic carbene modification on the catalytic performance of Pd clusters and nanoparticles in the Mizoroki--Heck reaction
Mendeleev Communications. 2026. V.36. N1. P.37-40. DOI: 10.71267/mencom.7806 WOS OpenAlex

Web of science:	WOS:001629991500010
OpenAlex:	W4416804501

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