Реферат: Rearrangement reactions constitute a critical facet of synthetic organic chemistry and demonstrate an attractive way to take advantage of existing structures to access various important molecular frameworks. The implementation of this rearrangement chemistry toward the construction of various medium-sized rings has played a considerable part. Several strategies entailing transition metal-free, organocatalysis, and photoredox conditions have been disclosed in the literature. It is the molecular rearrangements of D–A cyclopropanes that are discussed in this chapter. The chapter is divided into six different sections explaining the different types of rearrangement involved with the DACs, i.e. cyclopropane to alkene isomerization, vinylcyclopropane-to-cyclopentene isomerization, the Cloke–Wilson rearrangement, homo-Nazarov cyclization, homo-version of 3,3-sigmatropic shifts, and intramolecular nucleophilic ring opening–ring closure (INRORC) processes.

Библиографическая ссылка: Trushkov I.V. , Ivanova O.A.
Molecular Rearrangements inDonor–AcceptorCyclopropanes
В сборнике Donor Acceptor Cyclopropanes in Organic Synthesis. – Wiley‐VCH GmbH., 2024. – C.191-225. – ISBN 9783527835652. DOI: 10.1002/9783527835652.ch6 OpenAlex

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