Molecular Rearrangements inDonor–AcceptorCyclopropanes

Molecular Rearrangements inDonor–AcceptorCyclopropanes Review

Source

Donor Acceptor Cyclopropanes in Organic Synthesis
Compilation, Wiley‐VCH GmbH. 2024. ISBN 9783527835652.

Output data

Year: 2024, Article number : 6, Pages count : 35 DOI: 10.1002/9783527835652.ch6

Authors

Trushkov Igor V. ¹ , Ivanova Olga A. ²

Affiliations

1	1N.D. Zelinsky Institute of Organic Chemistry RAS, Laboratory of Directed Functionalization of Organic Molecular Systems, Leninsky Av., 47, Moscow, 119991 Russia
2	2M.V. Lomonosov Moscow State University, Department of Chemistry, Leninskie Gory, 1-3, Moscow, 119991 Russia

Rearrangement reactions constitute a critical facet of synthetic organic chemistry and demonstrate an attractive way to take advantage of existing structures to access various important molecular frameworks. The implementation of this rearrangement chemistry toward the construction of various medium-sized rings has played a considerable part. Several strategies entailing transition metal-free, organocatalysis, and photoredox conditions have been disclosed in the literature. It is the molecular rearrangements of D–A cyclopropanes that are discussed in this chapter. The chapter is divided into six different sections explaining the different types of rearrangement involved with the DACs, i.e. cyclopropane to alkene isomerization, vinylcyclopropane-to-cyclopentene isomerization, the Cloke–Wilson rearrangement, homo-Nazarov cyclization, homo-version of 3,3-sigmatropic shifts, and intramolecular nucleophilic ring opening–ring closure (INRORC) processes.

Trushkov I.V. , Ivanova O.A.
Molecular Rearrangements inDonor–AcceptorCyclopropanes
In compilation Donor Acceptor Cyclopropanes in Organic Synthesis. – Wiley‐VCH GmbH., 2024. – C.191-225. – ISBN 9783527835652. DOI: 10.1002/9783527835652.ch6 OpenAlex

OpenAlex:

W4391875325

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