Influence of steric factors on the reaction of hydrogenation of aromatic hydrocarbons in hydrogen storage systems

Influence of steric factors on the reaction of hydrogenation of aromatic hydrocarbons in hydrogen storage systems Научная публикация

Журнал

International Journal of Hydrogen Energy
ISSN: 0360-3199 , E-ISSN: 1879-3487

Вых. Данные

Год: 2025, Том: 141, Страницы: 1192-1198 Страниц : 7 DOI: 10.1016/j.ijhydene.2025.02.085

Авторы

Каlenchuk Alexander N. ^1,2 , Kultin Dmitry Yu ¹ , Lebedeva Olga K. ¹ , Tkachenko Olga ² , He Teng ³ , Kustov Leonid M. ^1,2

Организации

1	Department of Chemistry, Lomonosov Moscow State University, Moscow, 119991, Russia
2	N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Prospect 47, Moscow, 119991, Russia
3	Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, China

The process of hydrogenation of a mixture of aromatic hydrocarbons (benzene, ortho-, meta- and para-isomers of xylene, ethylbenzene, and biphenyl) on a Pd catalyst modified with nickel and chromium (Pd, 0.12 wt%, Ni, 3.8 wt%, Cr, 4.3 wt%) has been studied. The influence of steric factors on the reaction kinetics is investigated. It is shown that the presence of alkyl substituents results in a decrease of the reaction rates. Unlike substituted benzenes, the kinetics of hydrogenation of benzene and biphenyl is not hindered by the effects of the alkyl groups. The order of activity is as follows: benzene > biphenyl > toluene > ethylbenzene > m-xylene > p-xylene > o-xylene.

Каlenchuk A.N. , Kultin D.Y. , Lebedeva O.K. , Tkachenko O. , He T. , Kustov L.M.
Influence of steric factors on the reaction of hydrogenation of aromatic hydrocarbons in hydrogen storage systems
International Journal of Hydrogen Energy. 2025. V.141. P.1192-1198. DOI: 10.1016/j.ijhydene.2025.02.085 Scopus OpenAlex

Scopus:	2-s2.0-85217388467
OpenAlex:	W4407421860

БД	Цитирований
Scopus	2
OpenAlex	3