Germylenes and stannylenes based on amino bisphenols: synthesis, molecular and electronic structure

Germylenes and stannylenes based on amino bisphenols: synthesis, molecular and electronic structure Научная публикация

Журнал

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Вых. Данные

Год: 2026, Том: 75, Номер: 2, Страницы: 541-549 Страниц : 9 DOI: 10.1007/s11172-026-4906-5

Авторы

Timofeev S.V. ^1,2 , Zakharova E.A. ² , Zabalov M.V. ^2,3 , Mankaev B.N. ^2,4 , Syroeshkin M.A. ^2,4 , Lyssenko K.A. ² , Egorov M.P. ^2,4 , Karlov S.S. ^2,4

Организации

1	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Build. 1, 28 ul. Vavilova, 119334, Moscow, Russian Federation
2	Department of Chemistry, Lomonosov Moscow State University, Build. 3, 1 Leninskie Gory, 119991, Moscow, Russian Federation
3	N. N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 4 ul. Kosygina, 119991, Moscow, Russian Federation
4	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

New tetrylenes were synthesized by the reaction of amino bisphenols (2-HO-3-R1-5-MeC6H2CH2)2NR2 (R1 = But, CMe2Ph; R2 = Bu, Bn) with the Lappert’s tetrylenes M[N(SiMe3)2]2 (M = Ge, Sn). The structures of the synthesized complexes were confirmed by 1H, 13C, and 119Sn NMR spectroscopy and high-resolution mass spectrometry. The structure of the monomeric germylene with R1 = CMe2Ph and R2 = Bu was determined by X-ray diffraction. The frontier molecular orbitals of a number of complexed germylenes were analyzed in comparison to the uncomplexed analog (PBE0/L1). The additional coordination bond was found to affect the reactivity of germylenes in oxidative addition reactions. These data correlate with the relative chemical inertness of tetrylenes in the insertion reaction with iodomethane.

Timofeev S.V. , Zakharova E.A. , Zabalov M.V. , Mankaev B.N. , Syroeshkin M.A. , Lyssenko K.A. , Egorov M.P. , Karlov S.S.
Germylenes and stannylenes based on amino bisphenols: synthesis, molecular and electronic structure
Russian Chemical Bulletin. 2026. V.75. N2. P.541-549. DOI: 10.1007/s11172-026-4906-5 WOS Scopus OpenAlex

Тимофеев С.В. , Захарова Е.А. , Забалов М.В. , Манкаев Б.Н. , Сыроешкин М.А. , Лысенко К.А. , Егоров М.П. , Карлов С.С.
Гермилены и станнилены на основе аминобисфенолов: синтез, строение и электронная структура
Известия Академии наук. Серия химическая. 2026. Т.75. №2. С.541-549.

Поступила в редакцию:	19 июл. 2025 г.
Опубликована online:	11 апр. 2026 г.

≡ Web of science:	WOS:001738024100013
≡ Scopus:	2-s2.0-105035547499
≡ OpenAlex:	W7153444502