Photoinduced Synthesis of Iododifluoromethyl Sulfides from Organic Thiocyanates via Difluorinated Phosphonium Salts

Photoinduced Synthesis of Iododifluoromethyl Sulfides from Organic Thiocyanates via Difluorinated Phosphonium Salts Научная публикация

Журнал

Journal of Organic Chemistry
ISSN: 1520-6904 , E-ISSN: 0022-3263

Вых. Данные

Год: 2026, Том: 91, Номер: 32, Страницы: 11135-11140 Страниц : 6 DOI: 10.1021/acs.joc.6c01393

Авторы

Lozhkin Gregory A. ^1,2 , Trifonov Alexey L. ² , Dilman Alexander D. ²

Организации

1	Department of Chemistry, Lomonosov Moscow State University, Leninskie Gory 1−3, 119991 Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Leninsky Prospekt 47, 119991 Moscow, Russian Federation

A protocol for the synthesis of iododifluoromethyl sulfides from thiocyanates has been described. The method involves the formation of gem-difluorinated phosphonium salts from organic thiocyanates, difluorocarbene, and triphenylphosphine, followed by photoinduced phosphorus/iodine exchange. The photoreaction does not require a photocatalyst. The method allows the assembly of a similar ICF2-substituted selenide, as well as sulfides bearing the BrCF2 and ClCF2 groups.

Lozhkin G.A. , Trifonov A.L. , Dilman A.D.
Photoinduced Synthesis of Iododifluoromethyl Sulfides from Organic Thiocyanates via Difluorinated Phosphonium Salts
Journal of Organic Chemistry. 2026. V.91. N32. P.11135-11140. DOI: 10.1021/acs.joc.6c01393 WOS Scopus OpenAlex

Поступила в редакцию:	12 июн. 2026 г.
Опубликована online:	14 авг. 2026 г.

≡ Web of science:	WOS:001837541000001
≡ Scopus:	2-s2.0-105047320922
≡ OpenAlex:	W7172412571