Di(propargyl)nitramine: synthesis and reactivity | Sciact - научная деятельность

Di(propargyl)nitramine: synthesis and reactivity Научная публикация

Журнал

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Вых. Данные

Год: 2022, Том: 32, Номер: 2, Страницы: 218-220 Страниц : 3 DOI: 10.1016/j.mencom.2022.03.021

Авторы

Gribov Pavel S. ¹ , Mikhailova Maria V. ^2,1 , Kon'kova Tatiana S. ³ , Matyushin Yurii N. ³ , Sheremetev Aleksei B. ¹

Организации

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	Mendeleev University of Chemical Technology, 125047 Moscow, Russian Federation
3	N. N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 119991 Moscow, Russian Federation

An improved synthesis of (propargyl)nitramine and its pioneering conversion to di(propargyl)nitramine involve the alkylation of NH nitramines with propargyl halides or tosylate as the key steps. The standard (p° = 0.1 MPa) molar enthalpy of formation at 298.15 K for di(propargyl)nitramine was determined from the experimental standard molar energy of combustion in oxygen, measured by static bomb combustion calorimetry. Propargyl nitramines are suitable substrates for 1,3-dipolar cycloaddition reactions with azides, nitrile oxides and diazo compounds.

Gribov P.S. , Mikhailova M.V. , Kon'kova T.S. , Matyushin Y.N. , Sheremetev A.B.
Di(propargyl)nitramine: synthesis and reactivity
Mendeleev Communications. 2022. V.32. N2. P.218-220. DOI: 10.1016/j.mencom.2022.03.021 WOS Scopus OpenAlex

≡ Web of science:	WOS:000807715400022
≡ Scopus:	2-s2.0-85127366037
≡ OpenAlex:	W4221007170