Di(propargyl)nitramine: synthesis and reactivity

Di(propargyl)nitramine: synthesis and reactivity Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2022, Volume: 32, Number: 2, Pages: 218-220 Pages count : 3 DOI: 10.1016/j.mencom.2022.03.021

Authors

Gribov Pavel S. ¹ , Mikhailova Maria V. ^2,1 , Kon'kova Tatiana S. ³ , Matyushin Yurii N. ³ , Sheremetev Aleksei B. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	Mendeleev University of Chemical Technology, 125047 Moscow, Russian Federation
3	N. N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 119991 Moscow, Russian Federation

An improved synthesis of (propargyl)nitramine and its pioneering conversion to di(propargyl)nitramine involve the alkylation of NH nitramines with propargyl halides or tosylate as the key steps. The standard (p° = 0.1 MPa) molar enthalpy of formation at 298.15 K for di(propargyl)nitramine was determined from the experimental standard molar energy of combustion in oxygen, measured by static bomb combustion calorimetry. Propargyl nitramines are suitable substrates for 1,3-dipolar cycloaddition reactions with azides, nitrile oxides and diazo compounds.

Gribov P.S. , Mikhailova M.V. , Kon'kova T.S. , Matyushin Y.N. , Sheremetev A.B.
Di(propargyl)nitramine: synthesis and reactivity
Mendeleev Communications. 2022. V.32. N2. P.218-220. DOI: 10.1016/j.mencom.2022.03.021 WOS Scopus OpenAlex

≡ Web of science:	WOS:000807715400022
≡ Scopus:	2-s2.0-85127366037
≡ OpenAlex:	W4221007170