Spontaneous reaction of malonyl peroxides with methanol | Sciact

Spontaneous reaction of malonyl peroxides with methanol Научная публикация

Журнал

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Вых. Данные

Год: 2017, Том: 27, Номер: 3, Страницы: 243-245 Страниц : 3 DOI: 10.1016/j.mencom.2017.05.008

Авторы

Lapitskaya Margarita A. ¹ , Vil Vera A. ¹ , Vasil’eva Ludmila L. ¹ , Daeva Elena D. ¹ , Terent’ev Alexander O. ¹ , Pivnitsky Kasimir K. ¹

Организации

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

The spontaneous reaction of disubstituted malonyl peroxides (MPOs) with methanol affording monopermalonic acid monomethyl esters is fast (minutes) for lower homologues but is sharply decelerated (days) for the higher ones. Spirocyclopropyl-MPO is an exception in which the nucleophilic opening of the spiroactivated cyclopropane ring leads to 2,4-dimethoxy-2-carboxybutanoic acid.

Lapitskaya M.A. , Vil V.A. , Vasil’eva L.L. , Daeva E.D. , Terent’ev A.O. , Pivnitsky K.K.
Spontaneous reaction of malonyl peroxides with methanol
Mendeleev Communications. 2017. V.27. N3. P.243-245. DOI: 10.1016/j.mencom.2017.05.008 WOS Scopus OpenAlex

≡ Web of science:	WOS:000403984100008
≡ Scopus:	2-s2.0-85019999765
≡ OpenAlex:	W2620802825