Spontaneous reaction of malonyl peroxides with methanol

Spontaneous reaction of malonyl peroxides with methanol Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2017, Volume: 27, Number: 3, Pages: 243-245 Pages count : 3 DOI: 10.1016/j.mencom.2017.05.008

Authors

Lapitskaya Margarita A. ¹ , Vil Vera A. ¹ , Vasil’eva Ludmila L. ¹ , Daeva Elena D. ¹ , Terent’ev Alexander O. ¹ , Pivnitsky Kasimir K. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

The spontaneous reaction of disubstituted malonyl peroxides (MPOs) with methanol affording monopermalonic acid monomethyl esters is fast (minutes) for lower homologues but is sharply decelerated (days) for the higher ones. Spirocyclopropyl-MPO is an exception in which the nucleophilic opening of the spiroactivated cyclopropane ring leads to 2,4-dimethoxy-2-carboxybutanoic acid.

Lapitskaya M.A. , Vil V.A. , Vasil’eva L.L. , Daeva E.D. , Terent’ev A.O. , Pivnitsky K.K.
Spontaneous reaction of malonyl peroxides with methanol
Mendeleev Communications. 2017. V.27. N3. P.243-245. DOI: 10.1016/j.mencom.2017.05.008 WOS Scopus OpenAlex

≡ Web of science:	WOS:000403984100008
≡ Scopus:	2-s2.0-85019999765
≡ OpenAlex:	W2620802825