Light-Promoted Allylation of Iododifluoromethylated Alcohols Научная публикация
| Журнал |
European Journal of Organic Chemistry
ISSN: 1434-193X , E-ISSN: 1099-0690 |
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| Вых. Данные | Год: 2018, Том: 2018, Номер: 27-28, Страницы: 3834-3836 Страниц : 3 DOI: 10.1002/ejoc.201800543 | ||
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Реферат:
A method for the synthesis of β,β-difluorinated alcohols by the formal substitution of iodine in the iododifluoromethyl fragment by the allyl group is described. The reaction involves silylation of the starting alcohols with allyl(chloro)dimethylsilane followed by an light-promoted atom transfer process. The C,C-bond-forming event proceeds through 7-endo-trig radical cyclization.
Библиографическая ссылка:
Panferova L.I.
, Struchkova M.I.
, Dilman A.D.
Light-Promoted Allylation of Iododifluoromethylated Alcohols
European Journal of Organic Chemistry. 2018. V.2018. N27-28. P.3834-3836. DOI: 10.1002/ejoc.201800543 WOS Scopus OpenAlex
Light-Promoted Allylation of Iododifluoromethylated Alcohols
European Journal of Organic Chemistry. 2018. V.2018. N27-28. P.3834-3836. DOI: 10.1002/ejoc.201800543 WOS Scopus OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000439775200030 |
| Scopus: | 2-s2.0-85050391524 |
| OpenAlex: | W2801473988 |