Light-Promoted Allylation of Iododifluoromethylated Alcohols

Light-Promoted Allylation of Iododifluoromethylated Alcohols Full article

Journal

European Journal of Organic Chemistry
ISSN: 1434-193X , E-ISSN: 1099-0690

Output data

Year: 2018, Volume: 2018, Number: 27-28, Pages: 3834-3836 Pages count : 3 DOI: 10.1002/ejoc.201800543

Authors

Panferova Liubov I. ¹ , Struchkova Marina I. ¹ , Dilman Alexander D. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Leninsky prosp. 47, 119991 Moscow, Russian Federation

A method for the synthesis of β,β-difluorinated alcohols by the formal substitution of iodine in the iododifluoromethyl fragment by the allyl group is described. The reaction involves silylation of the starting alcohols with allyl(chloro)dimethylsilane followed by an light-promoted atom transfer process. The C,C-bond-forming event proceeds through 7-endo-trig radical cyclization.

Panferova L.I. , Struchkova M.I. , Dilman A.D.
Light-Promoted Allylation of Iododifluoromethylated Alcohols
European Journal of Organic Chemistry. 2018. V.2018. N27-28. P.3834-3836. DOI: 10.1002/ejoc.201800543 WOS Scopus OpenAlex

Web of science:	WOS:000439775200030
Scopus:	2-s2.0-85050391524
OpenAlex:	W2801473988

DB	Citing
OpenAlex	8
Scopus	8