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1,2,5-Thiadiazoles Обзор

Сборник Comprehensive Heterocyclic Chemistry IV
Сборник, 2022. ISBN 978-0-12-818656-5.
Вых. Данные Год: 2022, Том: 5, Страницы: 371-406 Страниц : 36 DOI: 10.1016/b978-0-12-409547-2.14813-9
Авторы Rakitin Oleg A. 1,2
Организации
1 N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia
2 Nanotechnology Education and Research Center, South Ural State University, Chelyabinsk, Russia

Реферат: Chapter 5.09 describes the chemistry of both monocyclic and benzo-fused 1,2,5-thiadiazoles over the period 2007–18. The Chapter is closely related to the previous Comprehensive Heterocyclic Chemistry issues CHEC(1984) (vol. 6, p. 513), CHEC-II(1996) (vol. 4, p. 355) and CHEC-III(1996) (vol. 5, p. 516). New methods for the ring synthesis including the formation of chiral 1,2,5-thiadiazolidine 1,1-dioxides from aziridines and diaziridines, and fused 1,2,5-thiadiazoles from 1,2,5-oxa- and 1,2,5-selenadiazoles are reported. The transition metal-catalyzed addition of various substrates to 1,2,5-thiadiazole 1,1-dioxides led to 2,3-dihydro[1,2,5]thiadiazole-1,1-diones in high yield and with high enantioselectivity. Important applications, especially in the field of organic photovoltaics are described.
Библиографическая ссылка: Rakitin O.A.
1,2,5-Thiadiazoles
В сборнике Comprehensive Heterocyclic Chemistry IV. 2022. – C.371-406. – ISBN 978-0-12-818656-5. DOI: 10.1016/b978-0-12-409547-2.14813-9 OpenAlex
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