Photoinduced Skeletal Rearrangement of Diarylethenes Comprising Oxazole and Phenyl Rings

Photoinduced Skeletal Rearrangement of Diarylethenes Comprising Oxazole and Phenyl Rings Научная публикация

Журнал

Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052

Вых. Данные

Год: 2014, Том: 16, Номер: 17, Страницы: 4532-4535 Страниц : 4 DOI: 10.1021/ol502073t

Авторы

Lvov Andrey G. ¹ , Shirinian Valerii Z. ¹ , Kachala Vadim V. ¹ , Kavun Alexey M. ¹ , Zavarzin Igor V. ¹ , Krayushkin Mikhail M. ¹

Организации

1	N. D. Zelinsky Institute of Organic Chemistry , RAS, 47, Leninsky prosp., 119991 Moscow, Russian Federation.

A novel photochemical rearrangement of diarylethenes bearing oxazole and benzene derivatives as aryl moieties that results in the formation of polyaromatic systems was investigated. The mechanism of the transformation includes photocyclization, sequential [1,9] and [1,3]-hydrogen shifts, as well as a lateral oxazole ring-opening process. It was shown that this reaction can be an effective synthetically preparative method for the preparation of naphthalene (polyaromatic) derivatives.

Lvov A.G. , Shirinian V.Z. , Kachala V.V. , Kavun A.M. , Zavarzin I.V. , Krayushkin M.M.
Photoinduced Skeletal Rearrangement of Diarylethenes Comprising Oxazole and Phenyl Rings
Organic Letters. 2014. V.16. N17. P.4532-4535. DOI: 10.1021/ol502073t WOS Scopus OpenAlex

≡ Web of science:	WOS:000341344600047
≡ Scopus:	2-s2.0-84914168943
≡ OpenAlex:	W2004191249