Photoinduced Skeletal Rearrangement of Diarylethenes Comprising Oxazole and Phenyl Rings

Photoinduced Skeletal Rearrangement of Diarylethenes Comprising Oxazole and Phenyl Rings Full article

Journal

Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052

Output data

Year: 2014, Volume: 16, Number: 17, Pages: 4532-4535 Pages count : 4 DOI: 10.1021/ol502073t

Authors

Lvov Andrey G. ¹ , Shirinian Valerii Z. ¹ , Kachala Vadim V. ¹ , Kavun Alexey M. ¹ , Zavarzin Igor V. ¹ , Krayushkin Mikhail M. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry , RAS, 47, Leninsky prosp., 119991 Moscow, Russian Federation.

A novel photochemical rearrangement of diarylethenes bearing oxazole and benzene derivatives as aryl moieties that results in the formation of polyaromatic systems was investigated. The mechanism of the transformation includes photocyclization, sequential [1,9] and [1,3]-hydrogen shifts, as well as a lateral oxazole ring-opening process. It was shown that this reaction can be an effective synthetically preparative method for the preparation of naphthalene (polyaromatic) derivatives.

Lvov A.G. , Shirinian V.Z. , Kachala V.V. , Kavun A.M. , Zavarzin I.V. , Krayushkin M.M.
Photoinduced Skeletal Rearrangement of Diarylethenes Comprising Oxazole and Phenyl Rings
Organic Letters. 2014. V.16. N17. P.4532-4535. DOI: 10.1021/ol502073t WOS Scopus OpenAlex

Web of science:	WOS:000341344600047
Scopus:	2-s2.0-84914168943
OpenAlex:	W2004191249

DB	Citing
OpenAlex	60
Scopus	63
Web of science	62