Evidence for “cocktail”-type catalysis in Buchwald–Hartwig reaction. A mechanistic study Научная публикация
Журнал |
Catalysis Science & Technology
ISSN: 2044-4761 , E-ISSN: 2044-4753 |
||||
---|---|---|---|---|---|
Вых. Данные | Год: 2021, Том: 11, Номер: 21, Страницы: 7171-7188 Страниц : 18 DOI: 10.1039/d1cy01601f | ||||
Авторы |
|
||||
Организации |
|
Реферат:
The mechanism of the C–N cross-coupling reaction, catalyzed by palladium complexes with N-heterocyclic carbene ligands (Pd/NHC), was evaluated in detail at the molecular and nanoscale levels. For the first time, the formation of a “cocktail”-type catalytic system was proven for the Buchwald–Hartwig reaction. The unique ability of the Pd/NHC system to generate several types of catalytic centers (Pd complexes, clusters and nanoparticles) and the involvement of complementary pathways (homogeneous and heterogeneous) were discovered to take place in a “one pot” manner directly in the reaction vessel. Access to various catalytic centers from a single and readily available Pd/NHC complex is the key to designing a universal catalytic system with adaptive tuning capability.
Библиографическая ссылка:
Prima D.O.
, Madiyeva M.
, Burykina J.V.
, Minyaev M.E.
, Boiko D.A.
, Ananikov V.P.
Evidence for “cocktail”-type catalysis in Buchwald–Hartwig reaction. A mechanistic study
Catalysis Science & Technology. 2021. V.11. N21. P.7171-7188. DOI: 10.1039/d1cy01601f WOS Scopus OpenAlex
Evidence for “cocktail”-type catalysis in Buchwald–Hartwig reaction. A mechanistic study
Catalysis Science & Technology. 2021. V.11. N21. P.7171-7188. DOI: 10.1039/d1cy01601f WOS Scopus OpenAlex
Идентификаторы БД:
Web of science: | WOS:000700914900001 |
Scopus: | 2-s2.0-85119011818 |
OpenAlex: | W3204878281 |