Visible‐Light Promoted Radical Fluoroalkylation of O‐ and N‐Substituted Alkenes Научная публикация
| Журнал |
Chemical Record
ISSN: 1527-8999 , E-ISSN: 1528-0691 |
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| Вых. Данные | Год: 2023, Том: 23, Номер: 9, Номер статьи : e202300038, Страниц : DOI: 10.1002/tcr.202300038 | ||
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Реферат:
Interaction of enol ethers enol acetates, enamides and enamines with fluorinated reagents may be considered as a reliable method for the synthesis of organofluorine compounds. While classic nucleophile/electrophile substitution or addition mechanisms cannot be realized for coupling of these components, their intrinsic reactivities are revealed with the aid of photoredox catalysis. A combination of these electron donating and accepting components provides a perfect balance needed for individual redox steps, which in some cases may proceed even without a photocatalyst. The same electronic factors also support the key C,C-bond forming event involving addition of fluorinated radical at the electron rich double bond.
Библиографическая ссылка:
Levin V.V.
, Dilman A.D.
Visible‐Light Promoted Radical Fluoroalkylation of O‐ and N‐Substituted Alkenes
Chemical Record. 2023. V.23. N9. e202300038 . DOI: 10.1002/tcr.202300038 WOS Scopus OpenAlex
Visible‐Light Promoted Radical Fluoroalkylation of O‐ and N‐Substituted Alkenes
Chemical Record. 2023. V.23. N9. e202300038 . DOI: 10.1002/tcr.202300038 WOS Scopus OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000963045400001 |
| Scopus: | 2-s2.0-85151544522 |
| OpenAlex: | W4362602300 |